Peculiarities of the Electron Structure of Pseudobinary Alloys (GeTe)m-(Sb2Te3)n

被引:1
作者
Orlov, V. G. [1 ]
Sergeev, G. S. [1 ]
机构
[1] Kurchatov Inst, Natl Res Ctr, Moscow 123182, Russia
关键词
PHASE-CHANGE MATERIALS; VALENCE-BOND THEORY; PAIR BONDS;
D O I
10.1134/S1063774519030209
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
?The electron band structure of GeTe, Sb2Te3, GeSb2Te4, and Ge2Sb2Te5 compounds has been calculated by the electron density functional method using the WIEN2k software package. These compounds belong to the class of (GeTe)(m)-(Sb2Te3)(n) pseudobinary alloys, which pass from the crystalline to the amorphous state and vice versa under laser irradiation or an electric pulse for extremely short times on the order of 1-100 ns. A detailed analysis of the parameters of critical points (maxima, minima, and inflection points) in the electron density distribution, located at the high-symmetry points of crystal structure, is performed. Characteristic values of the parameters of critical points in the electron density distribution are found for this class of materials.
引用
收藏
页码:422 / 427
页数:6
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