Potential and challenges of zeolite chemistry in the catalytic conversion of biomass

被引：679

作者：

Ennaert, Thijs ^{[1
]}

Van Aelst, Joost ^{[1
]}

Dijkmans, Jan ^{[1
]}

De Clercq, Rik ^{[1
]}

Schutyser, Wouter ^{[1
]}

Dusselier, Michiel ^{[1
]}

Verboekend, Danny ^{[1
]}

Sels, Bert F. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Fac Biosci Engn, Ctr Surface Chem & Catalysis, Celestijnenlaan 200f, B-3001 Heverlee, Belgium

来源：

CHEMICAL SOCIETY REVIEWS | 2016年 / 45卷 / 03期

关键词：

LEWIS-ACID SITES; SN-BETA ZEOLITES; DIESEL-RANGE ALKANES; HIGH-QUALITY DIESEL; STEAM-ASSISTED CONVERSION; LIQUID-PHASE DEHYDRATION; HIGH-SILICA ZEOLITES; ONE-POT SYNTHESIS; H-USY ZEOLITES; SOLID-ACID;

D O I：

10.1039/c5cs00859j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Increasing demand for sustainable chemicals and fuels has pushed academia and industry to search for alternative feedstocks replacing crude oil in traditional refineries. As a result, an immense academic attention has focused on the valorisation of biomass (components) and derived intermediates to generate valuable platform chemicals and fuels. Zeolite catalysis plays a distinct role in many of these biomass conversion routes. This contribution emphasizes the progress and potential in zeolite catalysed biomass conversions and relates these to concepts established in existing petrochemical processes. The application of zeolites, equipped with a variety of active sites, in Bronsted acid, Lewis acid, or multifunctional catalysed reactions is discussed and generalised to provide a comprehensive overview. In addition, the feedstock shift from crude oil to biomass involves new challenges in developing fields, like mesoporosity and pore interconnectivity of zeolites and stability of zeolites in liquid phase. Finally, the future challenges and perspectives of zeolites in the processing of biomass conversion are discussed.

引用

页码：584 / 611

页数：28

共 416 条

[1] Recent advances in lactic acid production by microbial fermentation processes [J].