Organometallic chemistry of silver and copper N-heterocyclic carbene complexes

被引:121
作者
Arnold, PL [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
关键词
D O I
10.1002/hc.10098
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The only stable organometallic carbene complexes of silver and copper are those of N-heterocyclic carbenes, since formally these robust divalent carbon ligands bind only by a donor interaction to the metal. A survey of the range of complexes that have now been reported is presented. (C) 2002 Wiley Periodicals, Inc.
引用
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页码:534 / 539
页数:6
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共 33 条
  • [1] A STABLE CRYSTALLINE CARBENE
    ARDUENGO, AJ
    HARLOW, RL
    KLINE, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
  • [2] The quest for stable carbenes
    Arduengo, AJ
    Krafczyk, R
    [J]. CHEMIE IN UNSERER ZEIT, 1998, 32 (01) : 6 - 14
  • [3] HOMOLEPTIC CARBENE SILVER(I) AND CARBENE COPPER(I) COMPLEXES
    ARDUENGO, AJ
    DIAS, HVR
    CALABRESE, JC
    DAVIDSON, F
    [J]. ORGANOMETALLICS, 1993, 12 (09) : 3405 - 3409
  • [4] CARBENE-LANTHANIDE COMPLEXES
    ARDUENGO, AJ
    TAMM, M
    MCLAIN, SJ
    CALABRESE, JC
    DAVIDSON, F
    MARSHALL, WJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) : 7927 - 7928
  • [5] Arduengo AJ, 1999, CHEM LETT, P1021
  • [6] Looking for stable carbenes: The difficulty in starting anew
    Arduengo, AJ
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) : 913 - 921
  • [7] Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper
    Arnold, PL
    Scarisbrick, AC
    Blake, AJ
    Wilson, C
    [J]. CHEMICAL COMMUNICATIONS, 2001, (22) : 2340 - 2341
  • [8] Metal vapor synthesis as a straightforward route to group 10 homoleptic carbene complexes
    Arnold, PL
    Cloke, FGN
    Geldbach, T
    Hitchcock, PB
    [J]. ORGANOMETALLICS, 1999, 18 (16) : 3228 - 3233
  • [9] N,N′-diferrocenyl-N-heterocyclic carbenes and their derivatives
    Bildstein, B
    Malaun, M
    Kopacka, H
    Wurst, K
    Mitterböck, M
    Ongania, KH
    Opromolla, G
    Zanello, P
    [J]. ORGANOMETALLICS, 1999, 18 (21) : 4325 - 4336
  • [10] N-heterocyclic carbene, silylene, and germylene complexes of MCl (M = Cu, Ag, Au). A theoretical study
    Boehme, C
    Frenking, G
    [J]. ORGANOMETALLICS, 1998, 17 (26) : 5801 - 5809