Enhanced Photocatalytic Degradation of 2-Butanone Using Hybrid Nanostructures of Gallium Oxide and Reduced Graphene Oxide Under Ultraviolet-C Irradiation

被引:9
作者
Bae, Hyun Jeong [1 ]
Yoo, Tae Hee [1 ]
Kim, Seungdu [1 ]
Choi, Wonhyeok [1 ]
Song, Yo Seung [1 ]
Kwon, Do-Kyun [1 ]
Cho, Byung Jin [2 ]
Hwang, Wan Sik [1 ]
机构
[1] Korea Aerosp Univ, Dept Mat Engn, Goyang 10540, South Korea
[2] Korea Adv Inst Sci & Technol, Sch Elect Engn, Daejeon 34141, South Korea
基金
新加坡国家研究基金会;
关键词
gallium oxide (Ga2O3); reduced graphene oxide (rGO); 2-butanone; volatile organic compounds (VOCs); photocatalytic oxidation (PCO); hydrothermal process; ultraviolet C (UVC) irradiation; WATER DECOMPOSITION; HYDROGEN-PRODUCTION; PERFORMANCE; BETA-GA2O3; OXIDATION; NANORODS; REMOVAL; HETEROJUNCTION; NANOCOMPOSITE; ALPHA-GA2O3;
D O I
10.3390/catal9050449
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hybrid nanostructures made of gallium oxide (Ga2O3) and reduced graphene oxide (rGO) are synthesized using a facile hydrothermal process method, where the Ga2O3 nanostructures are well dispersed on the rGO surface. The formed Ga2O3-rGO hybrids are characterized via Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), a diffuse reflectance Ultraviolet-visible-near infrared (UV-Vis-NIR) spectrophotometer, Brunauer-Emmett-Teller (BET), and photoluminescence (PL). Gas chromatography mass spectrometry (GC-MS) was used for analyzing volatile organic compounds (VOCs). The photocatalytic activity of the hybrid nanostructures is evaluated via the degradation of the 2-butanone, representing the VOCs under 254-nm radiation in the atmosphere. That activity is then compared to that of the Ga2O3 and commercial TiO2-P25. The Ga2O3-rGO hybrid shows enhanced photocatalytic degradation of 2-butanone compared to Ga2O3 and TiO2-P25, which is attributed to the enhanced specific surface area. The results indicate that the Ga2O3-rGO hybrid could be a promising method of enhancing photocatalytic activity and thereby effectively degrading VOCs, including the 2-butanone.
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页数:10
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