Enhanced Photocatalytic Degradation of 2-Butanone Using Hybrid Nanostructures of Gallium Oxide and Reduced Graphene Oxide Under Ultraviolet-C Irradiation

被引:8
作者
Bae, Hyun Jeong [1 ]
Yoo, Tae Hee [1 ]
Kim, Seungdu [1 ]
Choi, Wonhyeok [1 ]
Song, Yo Seung [1 ]
Kwon, Do-Kyun [1 ]
Cho, Byung Jin [2 ]
Hwang, Wan Sik [1 ]
机构
[1] Korea Aerosp Univ, Dept Mat Engn, Goyang 10540, South Korea
[2] Korea Adv Inst Sci & Technol, Sch Elect Engn, Daejeon 34141, South Korea
来源
CATALYSTS | 2019年 / 9卷 / 05期
基金
新加坡国家研究基金会;
关键词
gallium oxide (Ga2O3); reduced graphene oxide (rGO); 2-butanone; volatile organic compounds (VOCs); photocatalytic oxidation (PCO); hydrothermal process; ultraviolet C (UVC) irradiation; WATER DECOMPOSITION; HYDROGEN-PRODUCTION; PERFORMANCE; BETA-GA2O3; OXIDATION; NANORODS; REMOVAL; HETEROJUNCTION; NANOCOMPOSITE; ALPHA-GA2O3;
D O I
10.3390/catal9050449
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hybrid nanostructures made of gallium oxide (Ga2O3) and reduced graphene oxide (rGO) are synthesized using a facile hydrothermal process method, where the Ga2O3 nanostructures are well dispersed on the rGO surface. The formed Ga2O3-rGO hybrids are characterized via Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), a diffuse reflectance Ultraviolet-visible-near infrared (UV-Vis-NIR) spectrophotometer, Brunauer-Emmett-Teller (BET), and photoluminescence (PL). Gas chromatography mass spectrometry (GC-MS) was used for analyzing volatile organic compounds (VOCs). The photocatalytic activity of the hybrid nanostructures is evaluated via the degradation of the 2-butanone, representing the VOCs under 254-nm radiation in the atmosphere. That activity is then compared to that of the Ga2O3 and commercial TiO2-P25. The Ga2O3-rGO hybrid shows enhanced photocatalytic degradation of 2-butanone compared to Ga2O3 and TiO2-P25, which is attributed to the enhanced specific surface area. The results indicate that the Ga2O3-rGO hybrid could be a promising method of enhancing photocatalytic activity and thereby effectively degrading VOCs, including the 2-butanone.
引用
收藏
页数:10
相关论文
共 45 条
  • [1] Performance Enhancement of ZnO Photocatalyst via Synergic Effect of Surface Oxygen Defect and Graphene Hybridization
    Bai, Xiaojuan
    Wang, Li
    Zong, Ruilong
    Lv, Yanhui
    Sun, Yiqing
    Zhu, Yongfa
    [J]. LANGMUIR, 2013, 29 (09) : 3097 - 3105
  • [2] TiO2 photocatalytic oxidation of nitric oxide:: transient behavior and reaction kinetics
    Devahasdin, S
    Fan, C
    Li, KY
    Chen, DH
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 156 (1-3) : 161 - 170
  • [3] Colorimetric Polydiacetylene-Aerogel Detector for Volatile Organic Compounds (VOCs)
    Dolai, Susmita
    Bhunia, Susanta Kumar
    Beglaryan, Stella S.
    Kolusheva, Sofiya
    Zeiri, Leila
    Jelinek, Raz
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (03) : 2891 - 2898
  • [4] In situ plasmonic Ag nanoparticle anchored TiO2 nanotube arrays as visible-light-driven photocatalysts for enhanced water splitting
    Ge, Ming-Zheng
    Cao, Chun-Yan
    Li, Shu-Hui
    Tang, Yu-Xin
    Wang, Lu-Ning
    Qi, Ning
    Huang, Jian-Ying
    Zhang, Ke-Qin
    Al-Deyab, S. S.
    Lai, Yue-Kun
    [J]. NANOSCALE, 2016, 8 (09) : 5226 - 5234
  • [5] Enhanced photocatalytic performance of novel self-assembled floral β-Ga2O3 nanorods
    Girija, K.
    Thirumalairajan, S.
    Patra, Astam K.
    Mangalaraj, D.
    Ponpandian, N.
    Viswanathan, C.
    [J]. CURRENT APPLIED PHYSICS, 2013, 13 (04) : 652 - 658
  • [6] Incorporation of silver and gold nanostructures for performance improvement in P3HT: PCBM inverted solar cell with rGO/ZnO nanocomposite as an electron transport layer
    Gollu, Sankara Rao
    Sharma, Ramakant
    Srinivas, G.
    Kundu, Souvik
    Gupta, Dipti
    [J]. ORGANIC ELECTRONICS, 2016, 29 : 79 - 87
  • [7] Photocatalytic performance of α-, β-, and γ-Ga2O3 for the destruction of volatile aromatic pollutants in air
    Hou, Yidong
    Wu, Ling
    Wang, Xinchen
    Ding, Zhengxin
    Li, Zhaohui
    Fu, Xianzhi
    [J]. JOURNAL OF CATALYSIS, 2007, 250 (01) : 12 - 18
  • [8] Efficient decomposition of benzene over a β-Ga2O3 photocatalyst under ambient conditions
    Hou, Yidong
    Wang, Xinchen
    Wu, Ling
    Ding, Zhengxin
    Fu, Xianzhi
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (18) : 5799 - 5803
  • [9] Synthesis, characterization and photocatalytic activity of β-Ga2O3 nanostructures
    Hou, Yidong
    Zhang, Jinshui
    Ding, Zhengxin
    Wu, Ling
    [J]. POWDER TECHNOLOGY, 2010, 203 (03) : 440 - 446
  • [10] Understanding Hydrothermally Reduced Graphene Oxide Hydrogels: From Reaction Products to Hydrogel Properties
    Hu, Kaiwen
    Xie, Xingyi
    Szkopek, Thomas
    Cerruti, Marta
    [J]. CHEMISTRY OF MATERIALS, 2016, 28 (06) : 1756 - 1768