The insertion of sulfur dioxide into palladium-methyl bonds:: the synthesis and X-ray crystal structure of an unusual [(dppp)PdOS(Me)O]2[BAr′4]2 dimer

被引：20

作者：

Gates, DP ^{[1
]}

White, PS ^{[1
]}

Brookhart, M ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 01期

关键词：

D O I：

10.1039/a905993h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The migratory insertion of sulfur dioxide into the palladium(II)-methyl bond of [(dppp)Pd(Me)(OEt2)]BAr'(4) [Ar' = C6H3(CF3)(2)-3,5] to yield a unique dimeric eight-membered palladacycle was followed by NMR spectroscopy, and the product characterised by X-ray crystallography.

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页码：47 / 48

页数：2

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