Nitrogen and Sulfur Self-Doped Activated Carbon Directly Derived from Elm Flower for High-Performance Supercapacitors

被引:139
作者
Chen, Hui [1 ]
Yu, Feng [1 ]
Wang, Gang [1 ]
Chen, Long [1 ]
Dai, Bin [1 ]
Peng, Shanglong [2 ]
机构
[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832003, Peoples R China
[2] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China
来源
ACS OMEGA | 2018年 / 3卷 / 04期
基金
中国国家自然科学基金;
关键词
HIERARCHICALLY POROUS CARBON; MESOPOROUS CARBON; SURFACE-AREA; HIGH-ENERGY; NANOSHEETS; ELECTRODE; GRAPHENE; ARCHITECTURE; NANOSPHERES;
D O I
10.1021/acsomega.8b00210
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
N,S-Doped activated carbon was directly prepared via a facile and cost-efficient hydrothermal reaction, followed by alkali activation of elm flower (EL)-derived biomass. The EL-derived activated carbon (ELAC) had N and S contents of 2.21 and 6.06 atom %, respectively, in addition to a high Brunauer-Emmett-Teller (BET) surface area of 2048.6 m(2) g(-1) and moderate pore volume of 0.88 cm(3) g(-1). Owing to its high BET surface area and N/S functional groups, ELAC achieved a specific capacitance of 275 F g(-1) at a current density of 1 A g(-1) and retained a capacitance of 216 F g(-1) at 20 A g(-1). In addition, a symmetric supercapacitor based on N, S-self-doped ELAC electrode provided a capacitance of 62 F g(-1) at a current density of 10 A g(-1), with maximum energy and power densities of 16.8 Wh kg(-1) and 600 W kg(-1), respectively. The capacitance retention was also high, at 87.2%, at 4 A g(-1) after 5000 cycles.
引用
收藏
页码:4724 / 4732
页数:9
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