Enhanced Photocatalytic Activity of ZnO/CuO Nanocomposites Synthesized by Hydrothermal Method

被引:109
作者
Chang, Tongqin [1 ]
Li, Zijiong [1 ]
Yun, Gaoqian [1 ]
Jia, Yong [1 ]
Yang, Hongjun [1 ]
机构
[1] Zhengzhou Univ Light Ind, Dept Technol & Phys, Zhengzhou 450002, Peoples R China
关键词
Photocatalytic degradation; Nanocomposites; ZnO/CuO; Hydrothermal; ZNO PHOTOCATALYST; DEGRADATION; ORANGE; PERFORMANCE; FABRICATION; MORPHOLOGY; PROPERTY; SPHERES;
D O I
10.1007/BF03353746
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this paper, we have demonstrated a facile and low-cost synthesis of the ZnO/CuO nanocomposites by two-step hydrothermal methods. The photocatalytic properties of the as-synthesized ZnO/CuO nanocomposites have been evaluated by the photodegradation of methylene blue (MB) and methyleneorange (MO) under UV irradiation. Experimental results show that MB and MO can be degraded completely within 15 and 25 min by the ZnO/CuO nanocomposites and its photodegradation rate is 6 times faster than that of pure ZnO. This enhanced photocatalytic activity can be ascribed to the low recombination probability of photo-induced carriers due to the efficient charge transfer in the nanocomposites. The as-synthesized ZnO/CuO nanocomposite may be a promising candidate for dye photodegradation of wastewaters.
引用
收藏
页码:163 / 168
页数:6
相关论文
共 26 条
[11]   Fabrication and photocatalysis of CuO/ZnO nano-composites via a new method [J].
Liu, Zi-Ling ;
Deng, Jian-Cheng ;
Deng, Jing-Jing ;
Li, Fei-Fei .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2008, 150 (02) :99-104
[12]   Photocatalytic Treatment of Rhodamine 6G in Wastewater Using Photoactive ZnO [J].
Lutic, Doina ;
Coromelci-Pastravanu, Cristina ;
Cretescu, Igor ;
Poulios, Ioannis ;
Stan, Catalina-Daniela .
INTERNATIONAL JOURNAL OF PHOTOENERGY, 2012, 2012
[13]   Synthesis of Au-ZnO and Pt-ZnO nanocomposites by one-step flame spray pyrolysis and its application for photocatalytic degradation of dyes [J].
Pawinrat, Pongsapak ;
Mekasuwandumrong, Okorn ;
Panpranot, Joongjai .
CATALYSIS COMMUNICATIONS, 2009, 10 (10) :1380-1385
[14]   Preparation of a MWCNT/ZnO nanocomposite and its photocatalytic activity for the removal of cyanide from water using a laser [J].
Saleh, Tawfik A. ;
Gondal, M. A. ;
Drmosh, Q. A. .
NANOTECHNOLOGY, 2010, 21 (49)
[15]   Cost-effective large-scale synthesis of ZnO photocatalyst with excellent performance for dye photodegradation [J].
Tian, Chungui ;
Zhang, Qi ;
Wu, Aiping ;
Jiang, Meijia ;
Liang, Zhenglan ;
Jiang, Baojiang ;
Fu, Honggang .
CHEMICAL COMMUNICATIONS, 2012, 48 (23) :2858-2860
[16]   Enhanced photocatalytic performance of nanosized coupled ZnO/SnO2 photocatalysts for methyl orange degradation [J].
Wang, C ;
Wang, XM ;
Xu, BQ ;
Zhao, JC ;
Mai, BX ;
Peng, P ;
Sheng, GY ;
Fu, HM .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 168 (1-2) :47-52
[17]   Fabrication of CuO/T-ZnOw nanocomposites using photo-deposition and their photocatalytic property [J].
Wang, J. ;
Fan, X. M. ;
Wu, D. Z. ;
Dai, J. ;
Liu, H. ;
Liu, H. R. ;
Zhou, Z. W. .
APPLIED SURFACE SCIENCE, 2011, 258 (05) :1797-1805
[18]   Synthesis and photo-catalytic degradation property of nano structured-ZnO with different morphology [J].
Wang, Yuxin ;
Li, Xinyong ;
Lu, Guang ;
Chen, Guohua ;
Chen, Yongying .
MATERIALS LETTERS, 2008, 62 (16) :2359-2362
[19]   Controllable synthesis of ZnO nanoflowers and their morphology-dependent photocatalytic activities [J].
Wang, Yuxin ;
Li, Xinyong ;
Wang, Ning ;
Quan, Xie ;
Chen, Yongying .
SEPARATION AND PURIFICATION TECHNOLOGY, 2008, 62 (03) :727-732
[20]   CuO Nanoparticle Modified ZnO Nanorods with Improved Photocatalytic Activity [J].
Wei Ang ;
Xiong Li ;
Sun Li ;
Liu Yan-Jun ;
Li Wei-Wei .
CHINESE PHYSICS LETTERS, 2013, 30 (04)