The enhancement for SCR of NO by NH3 over the H2 or CO pretreated Ag/γ-Al2O3 catalyst

被引：16
|
作者：
Yu, Lemeng [1 ,2 ]
Zhong, Qin [1 ,2 ]
Zhang, Shule [1 ,2 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Nanjing AIREP Environm Protect Technol Co Ltd, Nanjing, Jiangsu, Peoples R China
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 24期
基金：
中国国家自然科学基金;
关键词：
SELECTIVE REDUCTION; AG/AL2O3; CATALYST; AMMONIA; MECHANISM; HYDROGEN; HYDROCARBONS; ADSORPTION; OXIDATION; NH3-SCR; ETHANOL;
D O I：
10.1039/c4cp00809j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
H-2 or CO pretreatment had been processed on the Ag/gamma-Al2O3 catalyst which significantly enhanced its NH3-SCR activity. The main purpose of this study was to prove that the impacts of pretreatment on silver species caused the enhancement. XRD, UV-vis, XPS, in situ FTIR and NO-TPD results showed the relationship between pretreatment, Ag species, NOX adsorption and NOX conversion. Extra nitrates were adsorbed on the Ag clusters which were produced by the pretreatment, thereby enhancing the activity. The reactivities between NO and NH3 had been studied. The difference between CO-pretreatment and H-2-pretreatment had also been discussed. Furthermore, the durability and stability of the pretreated sample were tested. Therefore, a modified Ag2O/Al2O3 catalyst for NH3-SCR was researched.
引用
收藏
页码：12560 / 12566
页数：7
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