Rotation of fullerene molecules in the crystal lattice of fullerene/porphyrin: C60 and Sc3N@C80

被引：13
作者：
Hao, Yajuan [1 ,2 ]
Wang, Yaofeng [1 ]
Spree, Lukas [1 ]
Liu, Fupin [1 ]
机构：
[1] Leibniz Inst Solid State & Mat Res IFW Dresden, Helmholtzstr 20, D-01069 Dresden, Germany
[2] Pingdingshan Univ, Sch Elect & Mech Engn, Pingdingshan 467000, Peoples R China
来源：
INORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 01期
关键词：
ENDOHEDRAL METALLOFULLERENES; PHASE-TRANSITION; NITRIDE;
D O I：
10.1039/d0qi01101k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dynamics of molecules in the solid-state is important to understand their physicochemical properties. The temperature-dependent dynamics of Sc3N@C-80 and C-60 in the crystal lattice containing nickel octaethylporphyrin (NiOEP) was studied with variable temperature X-ray diffraction (VT-XRD). The results indicate that the fullerene cages (both C-60 and C-80) in the crystal lattice present stronger libration than the co-crystallized NiOEP in the temperature range of 100-280 K. In contrast to the fullerene cage, the Sc3N cluster shows pronounced rotation roughly perpendicular to the plane of the co-crystallized NiOEP molecule driven by temperature. The obtained temperature dependent dynamic behavior of the Sc3N cluster is different from that of Ho2LuN and Lu3N, regardless of their rather similar structure, indicating the effect of the mass and size of the metal ions.
引用
收藏
页码：122 / 126
页数：5
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