Synthesis of Functionalized α-Pyrone and Butenolide Derivatives by Rhodium-Catalyzed Oxidative Coupling of Substituted Acrylic Acids with Alkynes and Alkenes

被引：193

作者：

Mochida, Satoshi ^{[1
]}

Hirano, Koji ^{[1
]}

Satoh, Tetsuya ^{[1
]}

Miura, Masahiro ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 16期

关键词：

C-H BONDS; INTERNAL ALKYNES; CARBOXYLIC-ACIDS; BENZOIC-ACIDS; ACTIVATION; ARYLATION; CLEAVAGE; ACRYLATES; ARYL; RH;

D O I：

10.1021/jo901077r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The straightforward and efficient synthesis of alpha-pyrone and butenolide derivatives has been achieved by the rhodium-catalyzed oxidative coupling reactions of substituted acrylic acids with alkynes and alkenes, respectively. Some alpha-pyrones obtained exhibit solid-state fluorescence.

引用

页码：6295 / 6298

页数：4

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