Nonenzymatic Hydrogen Peroxide Electrochemical Sensor Based on Au-HS/SO3H-PMO (Et) Nanocomposite

被引:4
作者
Jia, Feifei [1 ,2 ]
Zhong, Hui [1 ,2 ]
Zhu, Fengxia [1 ]
Li, Xiaorong [1 ]
Wang, Yinzhu [1 ]
Cheng, Zhipeng [1 ]
Zhang, Lili [1 ]
Sheng, Zhenhuan [1 ]
Guo, Liping [2 ]
机构
[1] Huaiyin Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Peoples R China
[2] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
基金
中国国家自然科学基金;
关键词
(Au-HS/SO3H-PMO (Et)) nanocomposite; Hydrogen peroxide; Nonenzymatic sensor; MESOPOROUS CARBON; GRAPHENE NANOSHEETS; MODIFIED ELECTRODE; NANOPARTICLES; GLUCOSE; H2O2; PERFORMANCE; HEXACYANOFERRATE; NANOSPHERES; NANOWIRES;
D O I
10.1002/elan.201400318
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A newly nonenzymatic sensor for hydrogen peroxide (H2O2) based on the (Au-HS/SO3H-PMO (Et)) nanocomposite is demonstrated. The electrochemical properties of the as-prepared nanocomposite were studied. It displayed an excellent performance towards H2O2 sensing in the linear response range from 0.20 mu M to 4.30 mu M (R=0.9999) with a sensitivity of 6.35 x 10(2) mu A mu M-1 cm(-2) and a low detection limit of 0.0499 mu M. Furthermore, it was not affected by electroactive interference species. These features proved that the modified electrode was suitable for determination of H2O2.
引用
收藏
页码:2244 / 2251
页数:8
相关论文
共 53 条
[1]  
[Anonymous], 2001, ELECTROCHEMICAL METH
[2]   Nanocomposites of palladium nanoparticle-loaded mesoporous carbon nanospheres for the electrochemical determination of hydrogen peroxide [J].
Bian, Xiaojun ;
Guo, Kai ;
Liao, Lei ;
Xiao, Jingjing ;
Kong, Jilie ;
Ji, Chang ;
Liu, Baohong .
TALANTA, 2012, 99 :256-261
[3]   Nonenzymatic amperometric sensor of hydrogen peroxide and glucose based on Pt nanoparticles/ordered mesoporous carbon nanocomposite [J].
Bo, Xiangjie ;
Ndamanisha, Jean Chrysostome ;
Bai, Jing ;
Guo, Liping .
TALANTA, 2010, 82 (01) :85-91
[4]  
Chen X. J., 2014, ELECTROANAL, V26, P1
[5]   Ultrafine palladium nanoparticles grown on graphene nanosheets for enhanced electrochemical sensing of hydrogen peroxide [J].
Chen, Xiao-mei ;
Cai, Zhi-xiong ;
Huang, Zhi-yong ;
Oyama, Munetaka ;
Jiang, Ya-qi ;
Chen, Xi .
ELECTROCHIMICA ACTA, 2013, 97 :398-403
[6]   Shape-controlled growth of surface-confined Au nanostructures for electroanalytical applications [J].
Das, Ashok Kumar ;
Raj, C. Retna .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2014, 717 :140-146
[7]   Determination of amino acids at a silver oxide/silver phosphate electrode and the analysis of structure-response relationships [J].
DeMott, JM ;
Jahngen, EGE .
ELECTROANALYSIS, 2005, 17 (07) :599-606
[8]   Presenting Analytical Performances of Electrochemical Sensors. Some Suggestions [J].
Desimoni, Elio ;
Brunetti, Barbara .
ELECTROANALYSIS, 2013, 25 (07) :1645-1651
[9]   A non-enzymatic hydrogen peroxide sensor based on poly(vinyl alcohol)-multiwalled carbon nanotubes-platinum nanoparticles hybrids modified glassy carbon electrode [J].
Fang, Yuxin ;
Zhang, Di ;
Qin, Xia ;
Miao, Zhiying ;
Takahashi, Shigehiro ;
Anzai, Jun-ichi ;
Chen, Qiang .
ELECTROCHIMICA ACTA, 2012, 70 :266-271
[10]   Te oxide nanowires as advanced materials for amperometric nonenzymatic hydrogen peroxide sensing [J].
Guascito, Maria Rachele ;
Chirizzi, Daniela ;
Malitesta, Cosimino ;
Siciliano, Tiziana ;
Tepore, Antonio .
TALANTA, 2013, 115 :863-869