The polymorphism of porphyrin 2D assemblies at the liquid-graphite interface: the effect of a polar solvent additive and a flexible spacer on the face-on and edge-on type molecular arrangements

被引：6
作者：
Adachi, Kenya [1 ]
Hirose, Takashi [2 ]
Matsuda, Kenji [1 ]
机构：
[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Nishikya Ku, Kyoto 6158510, Japan
[2] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 60期
关键词：
SUPRAMOLECULAR SELF-ASSEMBLIES; TETRAPHENYLPORPHYRIN; MONOLAYERS; MANIPULATION; CHEMISTRY; 2-D;
D O I：
10.1039/c9cc02579k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Self-assembly structures of 5,10,15,20-tetrakis(4-substituted phenyl)porphyrins at the liquid-graphite interface were investigated by scanning tunneling microscopy. We found that the presence of a small amount of a polar solvent, i.e., only 0.5 vol% of octanoic acid in phenyloctane, significantly affected the selective formation of the face-on polymorph over the edge-on one likely due to the solvent-molecule interactions at the 2D interface.
引用
收藏
页码：8836 / 8839
页数：4
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