Crystallization of calcium carbonate salts into beta-chitin scaffold

被引:52
作者
Falini, G [1 ]
Fermani, S [1 ]
Ripamonti, A [1 ]
机构
[1] Alma Mater Studiorum Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
关键词
beta-chitin; crystallization; calcium carbonate; aragonite; calcite; vaterite; squid pen;
D O I
10.1016/S0162-0134(02)00471-3
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Composites of beta-chitin with calcium carbonate polymorphs were prepared by precipitation of the mineral into a chitin scaffold by means of a double diffusion system. The beta-chitin was obtained from the pen of the Loligo sp. squid. The three main polymorphs of calcium carbonate: aragonite, calcite and vaterite, were observed. Their location within the matrix is a function of the polymorph. The supersaturation inside the compartmentalized space in the chitin governs the location and polymorphism of the crystals. (C) 2002 Elsevier Science Inc. All rights reserved.
引用
收藏
页码:475 / 480
页数:6
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