One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis

被引：102

作者：

Carboni, Aude ^{[1
]}

Dagousset, Guillaume ^{[1
]}

Magnier, Emmanuel ^{[2
]}

Masson, Geraldine ^{[1
]}

机构：

[1] CNRS, Inst Chim Subst Nat, Ctr Rech Gif, F-91198 Gif Sur Yvette, France

[2] Univ Versailles St Quentin, UMR 8180, Inst Lavoisier Versailles, F-78035 Versailles, France

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 91期

关键词：

VISIBLE-LIGHT PHOTOCATALYSIS; C-H TRIFLUOROMETHYLATION; CHIRAL PHOSPHORIC-ACID; BOND FORMATION; ELECTROPHILIC TRIFLUOROMETHYLATION; SODIUM TRIFLUOROMETHANESULFINATE; MEDIATED TRIFLUOROMETHYLATION; UNACTIVATED ALKENES; ORGANIC-SYNTHESIS; CONSTRUCTION;

D O I：

10.1039/c4cc07066f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein the first photoredox-catalyzed intermolecular aryl- and heteroaryltrifluoromethylation of alkenes. Under the optimized conditions using Umemoto's reagent as a CF3 source, a wide range of styrenes can be readily difunctionalized, affording the corresponding trifluoromethylated adducts in up to 99% yield.

引用

页码：14197 / 14200

页数：4

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