(2,4,6-trimethyldithiobenzoato-κ2S,S′)-bis(triphenylphosphine-κP)gold(I)

被引：2

作者：

Davis, Despina ^{[1
]}

Fronczek, Frank R. ^{[1
]}

Schuerman, Judith A. ^{[1
]}

Selbin, Joel ^{[1
]}

Watkins, Steven F. ^{[1
]}

机构：

[1] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806020460

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [Au(C10H8S2)-(C18H15P)(2)], consists of two independent molecules. The Au coordination environment can be described as a highly distorted tetrahedral arrangement (S2AuP2), but is more accurately described as a flattened trigonal pyramid defined by three normal covalent bonds (SAuP2), with a second S atom more distantly bonded to the Au atom.

引用

页码：M1524 / M1526

页数：3

共 13 条

[1] SYNTHESES, CHARACTERIZATIONS, LUMINESCENCE PROPERTIES, AND ELECTRONIC-STRUCTURES OF GOLD(I) BIS(PHOSPHINE)-XANTHATE COMPLEXES
ASSEFA, Z
STAPLES, RJ
FACKLER, JP
[J]. INORGANIC CHEMISTRY, 1994, 33 (13) : 2790 - 2798
[2] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI)
[J]. Journal of Applied Crystallography, 1997, 30 (pt 5)
[3] Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020
[4] ON ENANTIOMORPH-POLARITY ESTIMATION
FLACK, HD
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV): : 876 - 881
[5] Jian FF, 2003, CHINESE J INORG CHEM, V19, P761
[6] (N,N-Diisopropyldithiocarbamato- S,S′)bis(triphenylphosphine-P)gold(I) butane solvate
Jian, FF
Lu, L
Wang, X
Shanmuga, S
Raj, S
Razak, IA
Fun, HK
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : 939 - 940
[7] LANFREDI AMM, 1992, INORG CHIM ACTA, V192, P271
[8] 2-methyldithiobenzoato-κS)(triphenylphosphine-κO) gold(I)
Macalindong, JS
Fronczek, FR
Schuerman, JA
Selbin, J
Watkins, SF
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M889 - M890
[9] Nonius, 2000, COLLECT
[10] Processing of X-ray diffraction data collected in oscillation mode
Otwinowski, Z
Minor, W
[J]. MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 : 307 - 326

← 1 2 →