Experimental data of densities and viscosities of 1-propyl-2,3-dimethylimidazolium tetrafluoroborate ([PDMIM][BF4]) + H2O binary mixtures were measured over the entire mole fraction range from (298.15 to 343.15) K at atmospheric pressure. Excess molar volumes and viscosity deviations as a function of mole fraction average have been obtained and fitted to the Redlich-Kister equation. Estimated coefficients of the Redlich-Kister equation and standard error calculated from the Redlich-Kister equation to the experimental data were also presented.