Photocatalytic Hydrogen Production using Polymeric Carbon Nitride with a Hydrogenase and a Bioinspired Synthetic Ni Catalyst

被引：169
作者：
Caputo, Christine A. [1 ]
Gross, Manuela A. [1 ]
Lau, Vincent W. [2 ,3 ]
Cavazza, Christine [4 ]
Lotsch, Bettina V. [2 ,3 ]
Reisner, Erwin [1 ]
机构：
[1] Univ Cambridge, Dept Chem, Christian Doppler Lab Sustainable SynGas Chem, Cambridge CB2 1EW, England
[2] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
[3] Univ Munich, Dept Chem, D-81377 Munich, Germany
[4] Univ Grenoble Alpes, CNRS, CEA, IBS, F-38044 Grenoble, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 43期
基金：
英国工程与自然科学研究理事会;
关键词：
carbon nitride; enzyme catalysis; hydrogen production; hydrogenases; photocatalysis; VISIBLE-LIGHT; H-2; PRODUCTION; MOLECULAR CATALYSTS; ELECTRON-TRANSFER; SOLAR HYDROGEN; WATER; EVOLUTION; EFFICIENT; ELECTROCATALYSTS; SEMICONDUCTORS;
D O I：
10.1002/anie.201406811
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solar-light-driven H-2 production in water with a [NiFeSe]-hydrogenase (H(2)ase) and a bioinspired synthetic nickel catalyst (NiP) in combination with a heptazine carbon nitride polymer, melon (CNx), is reported. The semibiological and purely synthetic systems show catalytic activity during solar light irradiation with turnover numbers (TONs) of more than 50000molH(2)(molH(2)ase)(-1) and approximately 155molH(2)(molNiP)(-1) in redox-mediator-free aqueous solution at pH6 and 4.5, respectively. Both systems maintained a reduced photoactivity under UV-free solar light irradiation (>420 nm).
引用
收藏
页码：11538 / 11542
页数：5
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