Time-, wavelength, and polarization-resolved measurements of OH (A 2Σ+) picosecond laser-induced fluorescence in atmospheric-pressure flames

Laser-induced fluorescence of OH (A (2)Sigma(+), upsilon' = 1) was measured in hydrogen/oxygen and hydrogen/air/nitrogen flames using laser pulses of 80 psec duration. A 2D signal acquisition scheme simultaneously employed wavelength, temporal, and polarization resolution. The signals emitted in different rotational branches exhibit polarization-dependent intensities, depending on the rotational branch of the absorption line used. It is possible to select experimental conditions such that rotational and vibrational relaxation as well as electronic quenching can be monitored simultaneously. Advantages and limitations of the experimental approach are discussed. Numerical simulations are presented of the LIF spectra affected by energy transfer.