The reactions of phenyldimethylsilyllithium with nitriles

被引：11
作者：
Fleming, I
Solay, M
Stolwijk, F
机构：
[1] Department of Chemistry, Cambridge CB2 1EW, Lensfield Road
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 521卷 / 1-2期
关键词：
silicon; lithium; nitriles; brook rearrangement; acylsilane;
D O I：
10.1016/0022-328X(96)06220-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Phenyldimethylsilyllithium reacts with nitriles by several substantially different pathways depending upon the structure of the nitrile. The products include the acylsilane 2 from pivalonitrile (1), cumylsilane 5 from 2-phenylisobutyronitrile (4), the alpha-anion from phenylacetonitrile (9), and a mixture of benzil (15) and 2,4,5-triphenylimidazole (17) from benzonitrile (13).
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页码：121 / 124
页数：4
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