Step-by-step transformations of ferrocenyltellurium complexes of Group VIB metal carbonyls

被引：9

作者：

Mathur, Pradeep ^{[3
]}

Tauqeer, Mohd ^{[2
]}

Torubaev, Yury V. ^{[1
]}

Shaikh, Mobin M. ^{[3
]}

Lahiri, Goutam K. ^{[2
]}

Pasynskii, Alexander A. ^{[1
]}

Pavlova, Alina V. ^{[1
]}

机构：

[1] Chem RAS, NS Kurnakov Inst Gen & Inorgan, Moscow, Russia

[2] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

[3] Indian Inst Technol Indore, Sch Basic Sci, Indore, Madhya Pradesh, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 758卷

基金：

俄罗斯基础研究基金会;

关键词：

Organotellurium; Ferrocenyl; Metal carbonyl; Metal-metal bond; Short contacts; DIFERROCENYL DICHALCOGENIDES; DIPHENYLDITELLURIUM; CHROMIUM;

D O I：

10.1016/j.jorganchem.2014.02.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stepwise interactions of photochemically generated M(CO)(5)(THF) (M = Cr, Mo, W) with diferroce-nylditelluride initially generated mononuclear M(CO)(5)(Fc(2)Te(2)) followed by the bimetallic [M(CO)(5)](2)(mu-Fc(2)Te(2)) with terminal and bridged Fc(2)Te(2) moieties, respectively. On photolysis, [M(CO)(5)](2)(mu-Fc(2)Te(2)) transformed to FcTe bridged and M-M bonded "butterfly" complexes [(CO)(4)M(mu-FcTe)(2) via the elimination of two carbonyl groups. The solid state structures and Te-125 NMR spectral data of the new complexes and a new polymorphic form of Fc(2)Te(2) having remarkable intermolecular Te...pi-Cp short contacts (av. 3.5 angstrom) are discussed. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：55 / 59

页数：5

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