Thermoswitchable on-chip microsupercapacitors: one potential self-protection solution for electronic devices

被引:83
作者
Zhang, Panpan [1 ,2 ]
Wang, Jinhui [3 ,4 ]
Sheng, Wenbo [2 ,5 ]
Wang, Faxing [1 ,2 ]
Zhang, Jian [1 ,2 ]
Zhu, Feng [3 ,4 ]
Zhuang, Xiaodong [1 ,2 ]
Jordan, Rainer [2 ,5 ]
Schmidt, Oliver G. [2 ,3 ,4 ]
Feng, Xinliang [1 ,2 ]
机构
[1] Tech Univ Dresden, Sch Sci, Dept Chem & Food Chem, Chair Mol Funct Mat, Mommsenstr 4, D-01069 Dresden, Germany
[2] Tech Univ Dresden, Ctr Adv Elect Dresden Cfaed, D-01062 Dresden, Germany
[3] Tech Univ Chemnitz, Mat Syst Nanoelect, Reichenhainer Str 70, D-09107 Chemnitz, Germany
[4] IFW Dresden, Inst Integrat Nanosci, D-01069 Dresden, Germany
[5] Tech Univ Dresden, Sch Sci, Dept Chem & Food Chem, Chair Macromol Chem, Mommsenstr 4, D-01069 Dresden, Germany
关键词
ENERGY-STORAGE; SUPERCAPACITORS; CAPACITANCES; POLYMERS; DESIGN; FILMS;
D O I
10.1039/c8ee00365c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Efficient thermal protection is of great significance for electronic devices. Herein, we demonstrate a novel thermoswitchable microsupercapacitor (TS-MSC) with the self-protection function utilizing the thermodynamic behavior of a smart electrolyte, a lithium saltdissolved polymer sol, poly(N-isopropylacrylamide)-g-methylcellulose. Benefiting from the reversibility of ionic conductivity, the TS-MSC exhibited a broad temperature window (30-80 degrees C) and totally switch-off behavior at 80 degrees C, as well as excellent cycling stability upon heating/cooling cycles. In addition, the thermal protection of on-chip integrated MSCs in series or parallel was achieved by controlling a single TS-MSC connected with a computer CPU under different working conditions. Therefore, TS-MSCs are promising components in the thermal protection of practical on-chip electronic devices.
引用
收藏
页码:1717 / 1722
页数:6
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