A cadmium(II) coordination polymer:: Crystal structure and fluorescent property of [CdCl2(4,4′-bipyridine)]∞

被引：0

作者：

Lou, BY ^{[1
]}

Wang, RH ^{[1
]}

Xu, Y ^{[1
]}

Yuan, DQ ^{[1
]}

Zhou, YF ^{[1
]}

Hong, MC ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 23卷 / 07期

关键词：

cadmium(II); coordination polymer; crystal structure; fluorescence;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of L-histidine, CdCl(2)(.)2.5H(2)O and 4,4'-bipyridine in methane/water gave rise to a two-dimensional coordination polymer [CdCl2(4,4'-bipyridine)](infinity) which has been characterized by single-crystal X-ray diffraction. The polymer crystallizes in the orthorhombic system, space group Cmmm with a = 12.083 (7), b = 11.771(7), c = 3.781(2) Angstrom, V = 537.8(6) Angstrom(3), Z = 2, C10H8N2CdCl2, M-r = 339.48, D-c = 2.097 g/cm(3), F(000) = 328 and mu(MoKalpha) = 2.490 mm(-1). The final R = 0.0658 and wR = 0.1398 for 257 observed reflections with I greater than or equal to 2sigma(I).

引用

页码：747 / 750

页数：4

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