Palladium-Catalyzed Cross-Coupling Reactions of Bromo-Substituted Group 4 Metallocenes

被引：8

作者：

Ryabov, Alexey N. ^{[1
]}

Izmer, Vyatcheslav V. ^{[1
]}

Tzarev, Alexey A. ^{[1
]}

Uborsky, Dmitry V. ^{[1
]}

Asachenko, Andrey F. ^{[1
]}

Nikulin, Mikhail V. ^{[1
]}

Canich, Jo Ann M. ^{[2
]}

Voskoboynikov, Alexander Z. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[2] ExxonMobil Chem Co, Baytown, TX 77520 USA

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 13期

关键词：

RAY CRYSTAL-STRUCTURES; INTRAMOLECULAR 2+2 CYCLOADDITION; CHELATE-CONTROLLED SYNTHESIS; ANSA-METALLOCENES; METATHESIS ROUTE; POLYMERIZATION; COMPLEXES; ZIRCONIUM; DERIVATIVES; REACTIVITY;

D O I：

10.1021/om900353m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pd-catalyzed Negishi reactions of Zr and Hf complexes bearing eta(5)-4-bromo-2-methylindenyl and eta(5)-2-bromindenyl ligands with MeZnCl and varios aryl- and hetero-arylzinc reagents (RZnCl) give in high yields the respective complexes bearing eta(5)-4-R-2-methylindenyl and eta(5)-2-R-indenyl ligands, respectively.

引用

页码：3614 / 3617

页数：4

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