Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver(I) coordination frameworks with isonicotinic acid N-oxide

被引：57

作者：

Du, Miao ^{[1
]}

Li, Cheng-Peng ^{[1
]}

Guo, Jian-Hua ^{[1
]}

机构：

[1] Tianjin Normal Univ, Tianjin Key Lab Struct & Performance Funct Mol, Coll Chem & Life Sci, Tianjin 300387, Peoples R China

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 08期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; AG-AG BONDS; CRYSTAL-STRUCTURES; SOLID-STATE; BUILDING UNITS; POLYMERS; LIGAND; NETWORKS; COMPLEXES; SOLVENT;

D O I：

10.1039/b903074c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of isonicotinic acid N-oxide (HINO) with AgClO4 or AgBF4 under similar conditions unexpectedly generates two distinct crystalline products {[Ag-3(INO)(2)(HINO)(2)]center dot(ClO4)}(n) (1) and {[Ag(INO)]center dot(H2O)}(n) (2). Complex 1 consists of a 3-D cationic net with mixed-connected topology and the included perchlorate counterions, whereas 2 has a 3-D neutral open framework (4-connected crb topology) with the accommodation of lattice water. The anion exchange/competition and guest desorption/adsorption behavior have also been thoroughly explored.

引用

页码：1536 / 1540

页数：5

共 63 条

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