Dispersion behavior of hematoporphyrin in monomolecular film of stearic acid

被引:1
|
作者
Mu, J [1 ]
Feng, XS [1 ]
Li, JY [1 ]
Yang, KZ [1 ]
Chen, TF [1 ]
Jiang, L [1 ]
机构
[1] ACAD SINICA,INST PHOTOG CHEM,BEIJING 100101,PEOPLES R CHINA
基金
中国国家自然科学基金;
关键词
D O I
10.1080/01932699708943733
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dispersion characteristics of the monomolecular films of hematoporphyrin mixed with stearic acid has been studied. The average molecular areas of mixed monolayers coincided approximately with the ideal additivity rule when the ''solid'' films were extrapolated to zero surface pressure. The orientation of the macrocycles was given by infrared dichroism with the tilting angle of 10. 1 degrees to the plane of the film. The SERS of LB films deposited on silver island films was observed. The results showed that there are two possible contribution, i. e., electromagnetic and chemical interaction between the hematoporphyrin molecules and Ag island films.
引用
收藏
页码:243 / 249
页数:7
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