Total assignment of 1H and 13C NMR spectra of three triterpene saponins from roots of Silene vulgaris (Moench) Garcke

被引：22
作者：
Bouguet-Bonnet, S
Rochd, M
Mutzenhardt, P
Henry, M
机构：
[1] Univ Henri Poincare Nancy 1, CNRS, FRE 2415, Lab Methodol RMN,Fac Sci, F-54506 Vandoeuvre Les Nancy, France
[2] Univ Moulay, Fac Sci, Dept Biol, Meknes, Morocco
[3] Univ Henri Poincare Nancy 1, Lab Bot & Mycol, Fac Pharm, F-54001 Nancy, France
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 2002年 / 40卷 / 09期
关键词：
NMR; H-1; C-13; saponins; gypsogenin; 3-O-glucuronide; quillaic acid 3-O-glucuronide; 3-O-glycoside; Silene vulgaris; Caryophyllaceae;
D O I：
10.1002/mrc.1069
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The assignments of H-1 and C-13 NMR spectra for three new triterpene saponins from Silene vulgaris (gypsogenin 3-O-glucuronide, quillaic acid 3-O-glucuronide, and gypsogenin 3-O-glycoside) are reported. In addition to ID NMR methods, 2D NMR techniques (COSY, HSQC, HMBC, and HSQC-TOCSY) were used for the assignments. Copyright (C) 2002 John Wiley Sons, Ltd.
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页码：618 / 621
页数：4
相关论文
共 21 条
  • [1] H-1 AND C-13 ASSIGNMENTS FROM SENSITIVITY-ENHANCED DETECTION OF HETERONUCLEAR MULTIPLE-BOND CONNECTIVITY BY 2D MULTIPLE QUANTUM NMR
    BAX, A
    SUMMERS, MF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) : 2093 - 2094
  • [2] BOCK K, 1974, J CHEM SOC P2, P283
  • [3] Isolation and structure elucidation of a highly haemolytic saponin from the Merck saponin extract using high-field gradient-enhanced NMR techniques
    Delay, C
    Gavin, JA
    Aumelas, A
    Bonnet, PA
    Roumestand, C
    [J]. CARBOHYDRATE RESEARCH, 1997, 302 (1-2) : 67 - 78
  • [4] FENNANE M, 1999, SERIE BOT, V36, P228
  • [5] Gasiorowski K, 1999, PHARMAZIE, V54, P864
  • [6] Glensk M, 2000, JPC-J PLANAR CHROMAT, V13, P9
  • [7] Silenosides A-C, triterpenoid saponins from Silene vulgaris
    Glensk, M
    Wray, V
    Nimtz, M
    Schöpke, T
    [J]. JOURNAL OF NATURAL PRODUCTS, 1999, 62 (05): : 717 - 721
  • [8] Triterpenoid saponins from Quillaja saponaria
    Guo, SJ
    Kenne, L
    Lundgren, LN
    Rönnberg, B
    Sundquist, BG
    [J]. PHYTOCHEMISTRY, 1998, 48 (01) : 175 - 180
  • [9] HENRY M, 1982, PHYSIOL VEG, V20, P201
  • [10] BIOSYNTHESIS AND ACCUMULATION OF SAPONINS IN GYPSOPHILA-PANICULATA
    HENRY, M
    ROCHD, M
    BENNINI, B
    [J]. PHYTOCHEMISTRY, 1991, 30 (06) : 1819 - 1821
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