Chiral inclusion crystals constructed with achiral host and achiral guest molecules

被引:4
作者
Toda, F [1 ]
机构
[1] Okayama Univ Sci, Fac Sci, Dept Chem, Okayama 7000005, Japan
来源
ENANTIOMER | 2002年 / 7卷 / 2-3期
关键词
chiral inclusion crystals; generation of chirality in crystal; optical resolution; CD spectra in Nujol mulls; chiral helix; chiral twisting in crystal;
D O I
10.1080/10242430212198
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Achiral molecules of tetrakis(p-bromophenyl)ethylene and 2,3,6,7,10,11-hexahydroxy triphenylene were found to arrange in a chiral form in their inclusion crystal with an achiral guest molecule. The chiral arrangement of these achiral molecules was studied by X-ray analysis and CD spectral measurement in the solid state.
引用
收藏
页码:59 / 65
页数:7
相关论文
共 9 条
  • [1] Farina A, 1999, ANGEW CHEM INT EDIT, V38, P2433, DOI 10.1002/(SICI)1521-3773(19990816)38:16<2433::AID-ANIE2433>3.3.CO
  • [2] 2-4
  • [3] ABSOLUTE ASYMMETRIC-SYNTHESIS BY IRRADIATION OF CHIRAL CRYSTALS
    KAUPP, G
    HAAK, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05): : 694 - 695
  • [4] Absolute asymmetric synthesis from achiral molecules in the chiral crystalline environment
    Sakamoto, M
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (05) : 684 - 689
  • [5] Solvent-free organic synthesis
    Tanaka, K
    Toda, F
    [J]. CHEMICAL REVIEWS, 2000, 100 (03) : 1025 - 1074
  • [6] Chiral inclusion crystallization of tetra(p-bromophenyl)ethylene by exposure to the vapor of achiral guest molecules:: a novel racemic-to-chiral transformation through gas-solid reaction
    Tanaka, K
    Fujimoto, D
    Oeser, T
    Irngartinger, H
    Toda, F
    [J]. CHEMICAL COMMUNICATIONS, 2000, (05) : 413 - 414
  • [7] Chiral inclusion crystallization of achiral tetrakis(p-halophenyl)-ethylenes with achiral guest compounds
    Tanaka, K
    Fujimoto, D
    Altreuther, A
    Oeser, T
    Irngartinger, H
    Toda, F
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, (10): : 2115 - 2120
  • [8] Toda F, 2000, J PHYS ORG CHEM, V13, P39, DOI 10.1002/(SICI)1099-1395(200001)13:1<39::AID-POC203>3.0.CO
  • [9] 2-8