Chemistry, Physical Chemistry, and Uses of Molecular Fluorocarbon-Hydrocarbon Diblocks, Triblocks, and Related Compounds-Unique "Apblar" Components for Self-Assembled Colloid and Interface Engineering

被引：416
作者：
Krafft, Marie Pierre [1 ]
Riess, Jean G. [2 ]
机构：
[1] Univ Strasbourg, Inst Charles Sadron, SOFFT CNRS, F-67034 Strasbourg, France
[2] Harangoutte Les Roses, F-68160 Ste Croix Aux Mines, France
来源：
CHEMICAL REVIEWS | 2009年 / 109卷 / 05期
关键词：
SEMIFLUORINATED NORMAL-ALKANES; LIQUID-CRYSTALLINE PHASES; PERFLUORO-N-EICOSANE; DISSOCIATIVE ELECTRON-TRANSFER; SEMI-FLUORINATED ALKANES; FIELD-FLOW FRACTIONATION; LANGMUIR-BLODGETT-FILMS; ABSOLUTE RATE CONSTANTS; RADICAL CHAIN ADDITION; RED-CELL STORAGE;
D O I：
10.1021/cr800260k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The information regarding synthesis, structure, properties, and potential uses of fluorocarbon-hydrocarbon (FnHm) diblocks and related compounds, and self-assembled colloids and interfaces involving such compounds, is provided. The unique properties of FnHm diblocks are essentially determined by the forced covalent pairing of antipathetic F-chains and H-chains, resulting in an amphiphilic molecule. Terminally unsaturated diblocks are obtained from the iodinated diblocks by dehydrohalogenation with a strong base. The surface tension of neat liquid FnHm diblocks decreases when the weight of the F-chain is increased in the FnH(12-n) series and leveled off at 17.8 mN m-1 at 25°C. F12H2 behaves similar to F-n-alkanes at ambient temperature, adopting a hexagonal packing in a rhombohedral unit cell.
引用
收藏
页码：1714 / 1792
页数：79
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