Oxidative degradation of aqueous amine solutions of MEA, AMP, MDEA, Pz: A review

被引：118

作者：

Fredriksen, S. B. ^{[2
]}

Jens, Klaus-J. ^{[1
,3
]}

机构：

[1] Telemark Technol R&D Inst, Kjolnes Ring 30, N-3918 Porsgrunn, Norway

[2] Norner AS, N-3960 Porsgrunn, Norway

[3] Telemark Univ Coll, N-3901 Porsgrunn, Norway

来源：

GHGT-11 | 2013年 / 37卷

关键词：

CO2; capture; oxidative degradation; 2-Amino-1-ethanol; 2-Amino-2-methyl-1-propanol; N; N-Bis(2-hydroxyethyl)methylamine; Piperazine; CO2; CAPTURE; MONOETHANOLAMINE SOLUTIONS; POSTCOMBUSTION CAPTURE; CHLORINE DIOXIDE; SOLVENT; ABSORPTION; MECHANISMS; PATHWAYS; PRODUCTS; SCALE;

D O I：

10.1016/j.egypro.2013.06.053

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Alkanolamine based post-combustion capture processes (PCC) are currently the most attractive technologies for CO2 capture. Solvents are degraded in this service by flue gas components, for example oxygen. Solvent degradation can be classified into two reaction types: 1) amine oxidative degradation through a) autoxidation pathways, b) oxidation in the presence of metal ions and 2) thermal degradation including reactions in the presence of CO2. This study represents a literature survey of oxidative degradation (reaction type 1a) of 2-Amino-1-ethanol (MEA), 2-Amino-2-methyl-1-propanol (AMP), N,N-Bis(2-hydroxyethyl)methyl-amine (MDEA), and Piperazine (Pz). Thermal degradation products (reaction type 2) are included where appropriate in order to contribute to a more complete degradation overview of these compounds. (C) 2013 The Authors. Published by Elsevier Ltd. Open access under CC BY-NC-ND license. Selection and/or peer-review under responsibility of GHGT

引用

页码：1770 / 1777

页数：8

共 43 条

[1] [Anonymous], OIL GAS J
[2] [Anonymous], THESIS
[3] Oxide radical anion reactivity with aliphatic amino compounds in aqueous solution:: Comparison of H-atom abstraction from C-H and N-H groups by •O- and •OH radicals
Armstrong, DA
Asmus, KD
Bonifacic, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (12) : 2238 - 2246
[4] Thermal and oxidative disproportionation in amine degradation-O2 stoichiometry and mechanistic implications
Bedell, S. A.
Worley, C. M.
Darst, K.
Simmons, K.
[J]. INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2011, 5 (03) : 401 - 404
[5] Amine autoxidation in flue gas CO2 capture-Mechanistic lessons learned from other gas treating processes
Bedell, Stephen A.
[J]. INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2011, 5 (01) : 1 - 6
[6] Quaternaries as Intermediates in the Thermal and Oxidative Degradation of Alkanolamines
Bedell, Stephen A.
Worley, Clare M.
Al-Horr, Rida Sadek
McCrery, David A.
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (16) : 7147 - 7151
[7] Pathways for the formation of products of the oxidative degradation of CO2-loaded concentrated aqueous monoethanolamine solutions during CO2 absorption from flue gases
Bello, A
Idem, RO
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (04) : 945 - 969
[8] STABILIZATION OF MONOETHANOLAMINE SOLUTIONS IN CARBON DIOXIDE SCRUBBERS
BLACHLY, CH
RAVNER, H
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1966, 11 (03) : 401 - &
[9] Oxidative degradation of monoethanolamine
Chi, S
Rochelle, GT
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (17) : 4178 - 4186
[10] Closmann F. B., 2011, THESIS

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