Syntheses and crystal structures of cadmium(II) and cobalt(II) complexes with hydro[bis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl)] borate

被引：0

作者：

Shu Mou-Hai ^{[1
]}

Tu Chun-Lai

Cui Jing

Sun Jie

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 22卷 / 08期

关键词：

tripodal ligand; cadmium; cobalt; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new complexes CdL2 (1) and CoL2 (2) were synthesized by reactions of L {L=hydro[bis(3-p-tolyl-2thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl)]borate} with cadmium(II) and cobalt(H) acetate respectively, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S,H donor set defined by the sulphur and hydrogen atoms of two tripodal sulfur-rich ligands.

引用

页码：1507 / 1510

页数：4

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