Synthesis of orderly nanoporous aluminophosphate and zirconium phosphate materials and their catalytic applications

被引：9
作者：
Sreenivasulu, Peta [1 ,2 ]
Viswanadham, Nagabhatla [1 ,2 ]
Sharma, Trymbkesh [2 ]
Sreedhar, B. [3 ]
机构：
[1] AcSIR Indian Inst Petr, Dehra Dun, Uttar Pradesh, India
[2] CSIR, Indian Inst Petr, Catalysis & Convers Proc Div, Dehra Dun 248005, Uttar Pradesh, India
[3] CSIR, Indian Inst Chem Technol, New Delhi, India
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 47期
关键词：
MESOPOROUS TITANIUM PHOSPHATE; INORGANIC SOLID ACIDS; IRON PHOSPHATE; C-ALKYLATION; HYDROGEN-PRODUCTION; PARTIAL OXIDATION; EXCHANGE RESINS; OPEN-FRAMEWORK; O-ALKYLATION; N-BUTANE;
D O I：
10.1039/c4cc02614d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Amorphous alumino phosphate (AP) and zirconium phosphate (ZP) materials possessing an ordered nanoporosity have been successfully synthesized by a hydrothermal method using a P123 block co-polymer as the structure directing agent. The materials exhibited excellent catalytic activity towards selective alkylation of phenol with cyclohexanol, where AP showed as high as 100% selectivity to produce the industrially important O-alkylation product, while the corresponding ZP selectively produced a C-alkylation product (93% selectivity).
引用
收藏
页码：6232 / 6235
页数：4
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