Sulfur speciation in hard coal by means of a thermal decomposition method

A new method for the determination of organic and pyritic sulfur in hard coal is presented. The method is based on controlled thermal decomposition of coal sample in oxygen-free and oxygen atmospheres. The results for sulfur liberated in an argon atmosphere at temperatures up to 773 K were close to organic sulfur contents (S-org), although owing to the definition of 'organic sulfur' the values were not directly comparable. S-org contents are calculated from the difference between total sulfur content in coal and contents of this element in the form of sulfides, sulfates and pyrites. Sulfur contents, found in the second stage of analysis, were close to pyritic sulfur contents. The difference between total sulfur content and the sum of sulfur values obtained in stages I and II corresponded to sulfur contents in those samples which were neither decomposed nor oxidized at temperatures up to 1173 K. Although not comparable with such conventional concepts for industrial purposes these data are attractive due to the ease and rapidity of the new method for the control of sulfur streams in industrial processes.