Functionalized calix[4]arene-based receptor for saccharide recognition

被引：4
|
作者：
Mirza-Aghayan, Maryam [1 ]
Yarmohammadi, Masoud [1 ]
Mohammadian, Narges [1 ]
Zadmard, Reza [1 ]
Asadi, Fatemeh [1 ]
机构：
[1] CCERCI, Tehran, Iran
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2015年 / 83卷 / 1-2期
关键词：
Functionalized-calix[4]arene; Multicomponent reaction; Fluorescent titration; Saccharide recognition; SOLID-PHASE SYNTHESIS; ONE-POT SYNTHESIS; EFFICIENT SYNTHESIS; IMPROVED PROTOCOL; HANTZSCH; COMPLEXATION;
D O I：
10.1007/s10847-015-0540-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel class of functionalized-calix[4]arene such as 1,4-dihydropyridine-calix[4]arene, acridine-calix[4]arene and pyrimidine-calix[4]arene were synthesized using multicomponent reaction. These compounds have been characterized by H-1 NMR, C-13 NMR and HRMS. Fluorescent and (1)dH NMR titration investigations reveal that these derivatives have the high binding constant towards the monosaccharide and disaccharide in aqueous solution. The formation of complex was also supported by electrospray mass spectrometry.
引用
收藏
页码：53 / 61
页数：9
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