SYNTHESIS AND CATECHOLASE ACTIVITY OF Cu(II) AND Fe(III) COMPLEXES OF 4-METHYL-2-((PIPERIDIN-1-YL)METHYL)PHENOL

被引：0

作者：

Ayeni, Ayowole O. ^{[1
,2
]}

Watkins, Gareth M. ^{[1
]}

机构：

[1] Rhodes Univ, Dept Chem, ZA-6139 Grahamstown, South Africa

[2] Obafemi Awolowo Univ, Dept Chem, Ife 220005, Nigeria

来源：

SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY | 2020年 / 21卷 / 04期

关键词：

aminomethylation; monobase; oxidation; piperidine; quinone; COPPER(II) COMPLEXES; METAL-COMPLEXES; MANNICH BASE; MONONUCLEAR; LIGANDS; THIOCYANATE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study is aimed at evaluating the impact of N- and S- bonding modes of thiocyanate substituent on catecholase activity as its presence in the coordination sphere of the metal complex can either reduce catecholase activity or otherwise. 4-Methyl-2-((piperidin-1-yl)methyl) phenol - the Mannich base and its synthesized metal complexes were characterized by various spectroscopic techniques including NMR, IR, and UV-Vis spectroscopy. Turnover rates obtained from the Cu(II) and Fe(III) complexes ranged between 6.02 - 22.72 h(-1) with the thiocyanate mode in the Fe(III) complex leading to increased catecholase activity.

引用

页码：453 / 462

页数：10

共 30 条

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