A lead-porphyrin metal-organic framework: gas adsorption properties and electrocatalytic activity for water oxidation

被引：79

作者：

Dai, Fangna ^{[1
,2
]}

Fan, Weidong ^{[1
]}

Bi, Jiahui ^{[1
]}

Jiang, Peng ^{[2
]}

Liu, Dandan ^{[2
]}

Zhang, Xirui ^{[1
]}

Lin, Huan ^{[1
]}

Gong, Chuanfang ^{[1
]}

Wang, Rongming ^{[1
]}

Zhang, Liangliang ^{[1
]}

Sun, Daofeng ^{[1
]}

机构：

[1] China Univ Petr East China, Coll Sci, State Key Lab Heavy Oil Proc, Qingdao 266580, Shandong, Peoples R China

[2] China Univ Petr East China, Coll Chem Engn, Key Lab Catalysis, Qingdao 266580, Shandong, Peoples R China

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 01期

基金：

中国博士后科学基金;

关键词：

OXYGEN REDUCTION; BIFUNCTIONAL ELECTROCATALYSTS; HYDROGEN STORAGE; CARBON; MOFS; TRANSITION; SHEETS;

D O I：

10.1039/c5dt04025f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D non-interpenetrating porous metal-organic framework [Pb-2(H2TCPP)]center dot 4DMF center dot H2O (Pb-TCPP) (H6TCPP = 5,10,15,20-tetra (carboxyphenyl) porphyrin) was synthesized by employment of a robust porphyrin ligand. Pb-TCPP exhibits a one-dimensional channel possessing fairly good capability of gas sorption for N-2, H-2, Ar, and CO2 gases, and also features selectivity for CO2 over CH4 at 298 K. Furthermore, Pb-TCPP shows electrocatalytic activity for water oxidation in alkaline solution. It is the first 3D porous Pb-MOF that exhibits both gas adsorption properties and electrocatalytic activity for an oxygen evolution reaction (OER).

引用

页码：61 / 65

页数：5

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