Multiphoton transitions for the harmonic oscillator

被引:0
作者
Frey, J. G.
King, R. C.
Moss, R. E. [1 ]
机构
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
[2] Univ Southampton, Sch Math, Southampton SO17 1BJ, Hants, England
关键词
D O I
10.1080/00268970600798038
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
2- and 3-photon electric dipole transitions for the harmonic oscillator are shown to have zero intensity. This is extended to the general cases of Delta v = n and Delta v = n - 2 for n-photon transitions. Although not proved in general, it seems likely that all multiphoton transition moments vanish. This suggests that electric dipole multiphoton transition intensity is due to anharmonicity.
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页码:2523 / 2525
页数:3
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