Influence of Reduction Rate from Bi3+ to Bi(0) on Morphological Characteristics of Bi2Te3 Nanotubes
被引:1
作者:
Kim, Bin
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机构:
Korea Res Inst Chem Technol, Ctr Energy Mat Res, Taejon 305600, South Korea
Univ Sci & Technol, Dept Nanomat Sci & Engn, Taejon 305350, South KoreaKorea Res Inst Chem Technol, Ctr Energy Mat Res, Taejon 305600, South Korea
Kim, Bin
[1
,2
]
Jung, Sang Hee
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机构:
Korea Res Inst Chem Technol, Ctr Energy Mat Res, Taejon 305600, South KoreaKorea Res Inst Chem Technol, Ctr Energy Mat Res, Taejon 305600, South Korea
Jung, Sang Hee
[1
]
Park, Byung Ki
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h-index: 0
机构:
Korea Res Inst Chem Technol, Ctr Energy Mat Res, Taejon 305600, South KoreaKorea Res Inst Chem Technol, Ctr Energy Mat Res, Taejon 305600, South Korea
Park, Byung Ki
[1
]
机构:
[1] Korea Res Inst Chem Technol, Ctr Energy Mat Res, Taejon 305600, South Korea
[2] Univ Sci & Technol, Dept Nanomat Sci & Engn, Taejon 305350, South Korea
Alloys;
Chemical Synthesis;
Electron Microscopy;
Diffusion;
TELLURIUM;
D O I:
10.1166/jnn.2014.8786
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Bi2Te3 nanotubes were synthesized by alloying Te nanorods and Bi(0) metal reduced from Bi3+ using the solvothermal method. It was found that, when synthesizing Te nanorods, the concentration of NaOH was a greatly influential factor, where round-like Te nanorods were synthesized at the range of pH 12 similar to 13. Meanwhile, the alloying process between Bi(0) and Te nanorods was achieved through atomic diffusion in the interfacial surface of those two metals. The morphology of Bi2Te3 crystal was verified to be governed by the reduction rate changing to Bi(0) from Bi3+.