Pump-probe femtosecond-laser VUV REMPI technique applied to the study of highly excited states of allyl iodide

被引：5

作者：

Baklanov, AV

Maltsev, VP

Karlsson, L

Sassenberg, U

Persson, A

机构：

[1] UNIV STOCKHOLM,DEPT PHYS,S-11385 STOCKHOLM,SWEDEN

[2] LUND INST TECHNOL ATOM PHYS,S-22100 LUND,SWEDEN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1996年 / 92卷 / 10期

关键词：

D O I：

10.1039/ft9969201681

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The pump-probe REMPI technique has been used for a study of the femtosecond dynamics of the allyl iodide (Al) molecule excited in the VUV region. The VUV radiation was produced by non-resonant quintupling of Ti:S laser radiation in the mercury vapour or xenon gas. The lifetime of the excited state (hv approximate to 7.8 eV) of AI was found to be 290 +/- 30 fs. The nature of the process governing this decay time is discussed.

引用

页码：1681 / 1682

页数：2

共 15 条

[11] DISSOCIATION RATE CONSTANTS OF ALKYLBENZENES FROM HOT MOLECULES FORMED BY 158-NM (F2 LASER) IRRADIATION [J].