SRN1 and stille reactions:: A new synthetic strategy

被引：0

作者：

Corsico, EF ^{[1
]}

Rossi, RA ^{[1
]}

机构：

[1] Univ Nacl Cordoba, INFIQC, Dept Quim Organ, Fac Ciencias Quim, RA-5000 Cordoba, Argentina

来源：

MOLECULES | 2000年 / 5卷 / 03期

关键词：

D O I：

10.3390/50300431

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The photostimulated reaction of Me3Sn- ion with mono, di and trichloro arenes in liquid ammonia gave very good yields of stannanes by the S(RN)1 mechanism. These products reacted by a palladium-catalized cross coupling reaction with halobenzenes to give phenylated products also in very goods yields. Similar yields can be obtained in one-pot reactions.

引用

页码：431 / 432

页数：2