Electroconductivity investigations of the miscibility gap region in liquid In-Te alloys

被引:0
作者
Plevachuk, Y
Didoukh, V
Sokolovskii, B
机构
来源
PROCEEDINGS OF THE NINTH INTERNATIONAL CONFERENCE ON HIGH TEMPERATURE MATERIALS CHEMISTRY | 1997年 / 97卷 / 39期
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中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Electroconductivity measurements for liquid In-Te alloys were performed throughout the entire miscibility gap region, employing the original experimental technique for high temperature and high pressure investigations. The experiments were performed at temperatures up to 1200 K in neutral medium under excess pressure of argon gas (up to 50 MPa.). The liquid-liquid coexistence curve on the phase diagram of the In-Te system and the critical point data are determined from the measurements. The shape of the coexistence curve and its diameter behaviour are analyzed and critical indices are evaluated. A correlation of the metal-nonmetal electron transition with phase separation in liquid immiscible In-Te alloys is discussed briefly.
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页码:203 / 210
页数:8
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