The catalytic pyrolysis of food waste by microwave heating

被引:99
作者
Liu, Haili [1 ,2 ]
Ma, Xiaoqian [1 ]
Li, Longjun [1 ]
Hu, ZhiFeng [1 ]
Guo, Pingsheng [3 ]
Jiang, Yuhui [2 ]
机构
[1] S China Univ Technol, Elect Power Coll, Guangzhou 510640, Guangdong, Peoples R China
[2] Hunan Inst Humanities Sci & Technol, Dept Mech & Elect Engn, Loudi 417000, Peoples R China
[3] Guangxi Normal Univ, Phys Sci & Technol Inst, Guilin 541004, Peoples R China
关键词
Microwave pyrolysis; Food waste; Catalyst; Metal oxides; Chloride salts; MUNICIPAL SOLID-WASTE; ASSISTED PYROLYSIS; SEWAGE-SLUDGE; BIOMASS; OIL; GASIFICATION; GAS; TEMPERATURE; ADDITIVES; EMISSIONS;
D O I
10.1016/j.biortech.2014.05.020
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
This study describes a series of experiments that tested the use of microwave pyrolysis for treating food waste. Characteristics including rise in temperature, and the three-phase products, were analyzed at different microwave power levels, after adding 5% (mass basis) metal oxides and chloride salts to the food waste. Results indicated that, the metal oxides MgO, Fe2O3 and MnO2 and the chloride salts CuCl2 and NaCl can lower the yield of bio-oil and enhance the yield of gas. Meanwhile, the metal oxides MgO and MnO2 can also lower the low heating value (LHV) of solid residues and increase the pH values of the lower layer bio-oils. However, the chloride salts CuCl2 and NaCl had the opposite effects. The optimal microwave power for treating food waste was 400 W; among the tested catalysts, CuCl2 was the best catalyst and had the largest energy ratio of production to consumption (ERPC), followed by MnO2. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:45 / 50
页数:6
相关论文
共 35 条
[1]   Review of catalysts for tar elimination in Biomass gasification processes [J].
Abu El-Rub, Z ;
Bramer, EA ;
Brem, G .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (22) :6911-6919
[2]   Pyrolysis and gasification of food waste: Syngas characteristics and char gasification kinetics [J].
Ahmed, I. I. ;
Gupta, A. K. .
APPLIED ENERGY, 2010, 87 (01) :101-108
[3]  
Alfe D, 2005, PHYS REV B, V71, P1
[4]   Sintered alumina with low dielectric loss [J].
Alford, NM ;
Penn, SJ .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (10) :5895-5898
[5]   Phenol and phenolics from lignocellulosic biomass by catalytic microwave pyrolysis [J].
Bu, Quan ;
Lei, Hanwu ;
Ren, Shoujie ;
Wang, Lu ;
Holladay, John ;
Zhang, Qin ;
Tang, Juming ;
Ruan, Roger .
BIORESOURCE TECHNOLOGY, 2011, 102 (13) :7004-7007
[6]   Energy recovery from waste food by combustion or gasification with the potential for regenerative dehydration: A case study [J].
Caton, P. A. ;
Carr, M. A. ;
Kim, S. S. ;
Beautyman, M. J. .
ENERGY CONVERSION AND MANAGEMENT, 2010, 51 (06) :1157-1169
[7]   Catalytic effects of eight inorganic additives on pyrolysis of pine wood sawdust by microwave heating [J].
Chen, Ming-qiang ;
Wang, Jun ;
Zhang, Ming-xu ;
Chen, Ming-gong ;
Zhu, Xi-feng ;
Min, Fan-fei ;
Tan, Zhi-cheng .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2008, 82 (01) :145-150
[8]   Conventional and microwave induced pyrolysis of coffee hulls for the production of a hydrogen rich fuel gas [J].
Dominguez, A. ;
Menendez, J. A. ;
Fernandez, Y. ;
Pis, J. J. ;
Nabais, J. M. Valente ;
Carrott, P. J. M. ;
Carrott, M. M. L. Ribeiro .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2007, 79 (1-2) :128-135
[9]   Gas chromatographic-mass spectrometric study of the oil fractions produced by microwave-assisted pyrolysis of different sewage sludges [J].
Domínguez, A ;
Menéndez, JA ;
Inguanzo, M ;
Bernard, PL ;
Pis, JJ .
JOURNAL OF CHROMATOGRAPHY A, 2003, 1012 (02) :193-206
[10]  
G Ma, 2009, MOD FOOD SCI TECHNOL, V25, P1172