Synthesis, characterization, crystal structure and chemical behavior of [1,1-bis(diphenylphosphinomethyl)ethene]ruthenium(II) complex toward primary alkylamine addition

被引：20

作者：

Warad, Ismail Khalil ^{[1
]}

Siddiqui, M. Rafiq H. ^{[1
]}

Al-Resayes, Saud ^{[1
]}

Al-Warthan, Abdulrahman ^{[1
]}

Mahfouz, Refaat ^{[1
]}

机构：

[1] King Saud Univ, Dept Chem, Riyadh 11451, Saudi Arabia

来源：

TRANSITION METAL CHEMISTRY | 2009年 / 34卷 / 03期

关键词：

SUPPORTED ORGANOMETALLIC COMPLEXES; ASYMMETRIC HYDROGENATION; DIAMINE(ETHER-PHOSPHINE)RUTHENIUM(II) COMPLEXES; RUTHENIUM(II) COMPLEXES; STEREOSELECTIVE HYDROGENATION; CATALYTIC-ACTIVITY; KETONES; LIGANDS; INTERPHASES; CHEMISTRY;

D O I：

10.1007/s11243-009-9201-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the ruthenium phosphine complex [RuCl(2)(PPh(3))(3)] 1 with an unsaturated functionalized diphosphine ligand, namely 1,1-bis(diphenyl-phosphinomethyl)ethene, H(2)C=C(CH(2)PPh(2))(2), (dppme) gave trans-Cl(2)Ru(dppme)(2) 2. Complex 2 served as a precursor for the synthesis of trans-Cl(2)Ru(dppme)(alkylamine)(2) complexes 3-5 by reaction with RNH(2). All these complexes were characterized by spectroscopic techniques and by elemental analysis. The solid-state structure of complex 2 was determined by X-ray crystallography.

引用

页码：347 / 352

页数：6

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