Thermal activation of methane by tetranuclear [V4O10]+

被引：218
作者：
Feyel, Sandra
Doebler, Jens
Schroeder, Detlef
Sauer, Joachim
Schwarz, Helmut
机构：
[1] Humboldt Univ, Inst Chem, D-10099 Berlin, Germany
[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 28期
关键词：
C-H activation; density functional calculation; mass spectrometry; molecular dynamics; vanadium oxides;
D O I：
10.1002/anie.200600188
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Hand in hand: In a combination of experimental (mass spectrometry) and theoretical (density functional theory) studies [V 4O10]+ is described as the first polynuclear transition-metal oxide capable of activating methane at room temperature (see picture). The [V4O10]+ cation can be considered a prototype of oxide clusters of early 3d transition metals. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：4681 / 4685
页数：5
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