Rhodium-Catalyzed Tandem Cyclization/Si-C Activation Reaction for the Synthesis of Siloles

被引：59

作者：

Zhang, Qing-Wei ^{[1
,2
]}

An, Kun ^{[1
,2
]}

He, Wei ^{[1
,2
]}

机构：

[1] Tsinghua Univ, Sch Med, Beijing 100084, Peoples R China

[2] Tsinghua Univ, Tsinghua Peking Joint Ctr Life Sci, Beijing 100084, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 22期

基金：

中国博士后科学基金;

关键词：

heterocycles; luminescence; rhodium; silicon; synthetic methods; CARBON-SILICON BOND; BENZOSILOLE DERIVATIVES; PHOTOPHYSICAL PROPERTIES; ASYMMETRIC-SYNTHESIS; ALKYNES; CLEAVAGE; CYCLOADDITION; POLYMERS; SILANES; SILAFLUORENES;

D O I：

10.1002/anie.201400828

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Siloles represent an important emerging class of photoluminescent materials. Reported herein is a new synthetic strategy involving a tandem cyclization/Si-C activation reaction featuring high efficiency, wide substrate scope, and practical utility. This method enabled the first synthesis of benzofuran siloles as well as rapid access to conjugated siloles. During the course of the study we also uncovered an unusual yet general Si-C(sp(2)) activation in the presence of p acids.

引用

页码：5667 / 5671

页数：5

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