Photocatalytic hydrogen production from water using porous material [Ru2(p-BDC)2]n

被引：209

作者：

Kataoka, Yusuke ^{[1
]}

Sato, Konomi ^{[1
]}

Miyazaki, Yuhei ^{[1
]}

Masuda, Kazuki ^{[1
]}

Tanaka, Hiroshi ^{[1
]}

Naito, Shuichi ^{[2
]}

Mori, Wasuke ^{[1
]}

机构：

[1] Kanagawa Univ, Fac Sci, Dept Chem, Kanagawa 2591293, Japan

[2] Kanagawa Univ, Fac Engn, Dept Appl Chem, Kanagawa 2218686, Japan

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2009年 / 2卷 / 04期

关键词：

GAS-OCCLUSION PROPERTIES; TRANS-TRANS-MUCONATE; DICARBOXYLATES FUMARATE; CATALYTIC PERFORMANCE; MICROPOROUS MATERIALS; POLYMER; TEREPHTHALATE; RUTHENIUM; COMPLEX; DESIGN;

D O I：

10.1039/b814539c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have detected the first example of open porous metal-organic frameworks (MOFs) that functions as an activity site for the reduction of water into hydrogen molecules in the presence of Ru(bpy)(3)(2+), MV2+, and EDTA-2Na under visible light irradiation. This activity is highly efficient: the turnover number based on MOFs and the apparent quantum yield are 8.16 and 4.82%, respectively. Furthermore, this material enables the adsorption of various gases into its pores; its hydrogen uptake capacity is 1.2 wt% at 77.4 K.

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页码：397 / 400

页数：4

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