Solubility and thermodynamic properties of N-acetylglucosamine in mono-solvents and binary solvents at different temperatures

被引：11

作者：

Fang, Wenjie ^{[1
]}

Chen, Kui ^{[1
]}

Ji, Lijun ^{[1
]}

Zhu, Jiawen ^{[1
]}

Wu, Bin ^{[1
]}

Wu, Yanyang ^{[1
]}

机构：

[1] East China Univ Sci & Technol, Chem Engn Res Ctr, Shanghai, Peoples R China

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2019年 / 57卷 / 05期

关键词：

N-acetylglucosamine; solubility; thermodynamic model; thermodynamic properties; DISSOLUTION THERMODYNAMICS; D-GLUCOSAMINE; ETHANOL; MIXTURES; EXPRESSION; METHANOL; CHITIN; PURE;

D O I：

10.1080/00319104.2018.1506921

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solubility data of N-acetylglucosamine in five pure solvents (water, methanol, ethanol, n-propanol and acetone) and two binary solvents (water + ethanol, water + acetone) were measured by gravimetric method at temperatures from 283.15 to 313.15 K under atmosphere pressure (p = 101 kPa). The solubility data show that the solubility of N-acetylglucosamine in pure solvents increases with the increasing temperature and the solubility in binary solvents is affected by temperature and solvent composition. The solubility data of N-acetylglucosamine in pure solvents were correlated by Van't Hoff model, modified Apelblat model, lambda h model and the modified Apelblat model has the best performance. Jouyban-Acree model was used to correlate the solubility data of N-acetylglucosamine in binary solvents and the fitting performance was well. The dissolution thermodynamic properties of N-acetylglucosamine in all solvents were also estimated in this work. The experimental data will be helpful for purification process of N-acetylglucosamine in industry.

引用

页码：587 / 599

页数：13

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