A hybrid cobalt hydroxyacetate magnet: ionothermal synthesis, 3-D Co-O-Co connectivity and spin glass behavior

被引：6
作者：
Wu, Guo-Xing [1 ,2 ]
Wu, Hai-Shun [1 ]
Zhang, Xian-Ming [1 ]
机构：
[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Struct Inorgan & Magnet Mat Key Lab, Educ Minist, Linfen 041004, Peoples R China
[2] Lvliang Higher Coll, Lishi 033000, Peoples R China
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 05期
关键词：
SINGLE-CHAIN MAGNET; HYDROTHERMAL SYNTHESIS; FRAMEWORK MATERIALS; ORGANIC FRAMEWORK;
D O I：
10.1039/b919966g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An ionothermal reaction has generated a cobalt hydroxyacetate magnet that contains a three-dimensional Co-O-Co framework consisting of vertex-sharing octahedral chains bridged by another octahedra via edge-sharing and shows spin glass behavior.
引用
收藏
页码：1179 / 1181
页数：3
相关论文
共 27 条
[1]   CO(OH)(NO3)BULLET-H2O - A NOVEL DOUBLE-CHAIN COMPOUND WITH COMPETING INTERACTIONS [J].
ANGELOV, S ;
DRILLON, M ;
ZHECHEVA, E ;
STOYANOVA, R ;
BELAICHE, M ;
DERORY, A ;
HERR, A .
INORGANIC CHEMISTRY, 1992, 31 (08) :1514-1517
[2]  
[Anonymous], 1993, SPIN GLASSES EXPT IN
[3]  
Casey A.T., 1976, Theory and Applications of Molecular Paramagnetism, P135
[4]   Layered metal organosulfides:: hydrothermal synthesis, structure and magnetic behaviour of the spin-canted magnet Co(1,2-(O2C)(S)C6H4) [J].
Cave, D ;
Gascon, JM ;
Bond, AD ;
Teat, SJ ;
Wood, PT .
CHEMICAL COMMUNICATIONS, 2002, (10) :1050-1051
[5]  
Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
[6]  
2-U
[7]   Structural diversity and chemical trends in hybrid inorganic-organic framework materials [J].
Cheetham, Anthony K. ;
Rao, C. N. R. ;
Feller, Russell K. .
CHEMICAL COMMUNICATIONS, 2006, (46) :4780-4795
[8]   A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation [J].
Cheng, Xiao-Ning ;
Zhang, Wei-Xiong ;
Lin, Yan-Yong ;
Zheng, Yan-Zhen ;
Chen, Xiao-Ming .
ADVANCED MATERIALS, 2007, 19 (11) :1494-+
[9]  
de Jongh L.J., 1990, MAGNETIC PROPERTIES
[10]   Cobalt(II) formate hydroxide [J].
Fu, YL ;
Ren, JL ;
Xu, ZW ;
Ng, SW .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M2395-M2396
123