All solid-state lithium-oxygen batteries with MOF-derived nickel cobaltate nanoflake arrays as high-performance oxygen cathodes

被引：17
作者：
Gong, Hao [1 ,2 ]
Xue, Hairong [2 ]
Lu, Xueyi [2 ]
Gao, Bin [1 ]
Wang, Tao [1 ]
He, Jianping [1 ]
Ma, Renzhi [2 ]
机构：
[1] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Technol, Jiangsu Key Lab Electrochem Energy Storage Techno, Nanjing 210016, Jiangsu, Peoples R China
[2] NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 72期
基金：
中国国家自然科学基金;
关键词：
AIR BATTERIES; ELECTROLYTE; CONDUCTIVITY; CATALYST; FOAM;
D O I：
10.1039/c9cc05685h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solid-state Li1+xAlxGe2-x(PO4)(3) electrolytes with high ionic conductivity were prepared and successfully applied in lithium-oxygen batteries (LOBs). Combined with MOF-derived NiCo2O4 cathodes, the solid-state LOBs deliver a high discharge capacity and good rate performance. Moreover, enabled by such a bifunctional cathode, the as-assembled solid-state LOBs show enhanced reversibility and long-term cycling stability over 90 cycles.
引用
收藏
页码：10689 / 10692
页数：4
相关论文
共 37 条
  • [1] MOF Derived Nonstoichiometric NixCo3-xO4-y Nanocage for Superior Electrocatalytic Oxygen Evolution
    Antony, Rajini P.
    Satpati, Ashis K.
    Bhattacharyya, Kaustava
    Jagatap, Bhagawantrao N.
    [J]. ADVANCED MATERIALS INTERFACES, 2016, 3 (20):
  • [2] IONIC-CONDUCTIVITY AND SINTERABILITY OF LITHIUM TITANIUM PHOSPHATE SYSTEM
    AONO, H
    SUGIMOTO, E
    SADAOKA, Y
    IMANAKA, N
    ADACHI, G
    [J]. SOLID STATE IONICS, 1990, 40-1 : 38 - 42
  • [3] Aurbach D, 2016, NAT ENERGY, V1, DOI [10.1038/NENERGY.2016.128, 10.1038/nenergy.2016.128]
  • [4] Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
  • [5] A high performance O2 selective membrane based on CAU-1-NH2@polydopamine and the PMMA polymer for Li-air batteries
    Cao, Lujie
    Lv, Fucong
    Liu, Ying
    Wang, Wenxi
    Huo, Yifeng
    Fu, Xianzhu
    Sun, Rong
    Lu, Zhouguang
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (21) : 4364 - 4367
  • [6] Hierarchical Structures Based on Two-Dimensional Nanomaterials for Rechargeable Lithium Batteries
    Cong, Lina
    Xie, Haiming
    Li, Jinghong
    [J]. ADVANCED ENERGY MATERIALS, 2017, 7 (12)
  • [7] Co9S8@carbon porous nanocages derived from a metal-organic framework: a highly efficient bifunctional catalyst for aprotic Li-O2 batteries
    Dou, Yaying
    Lian, Ruqian
    Zhang, Yantao
    Zhao, Yingying
    Chen, Gang
    Wei, Yingjin
    Peng, Zhangquan
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (18) : 8595 - 8603
  • [8] Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries
    Gao, Zhonghui
    Sun, Huabin
    Fu, Lin
    Ye, Fangliang
    Zhang, Yi
    Luo, Wei
    Huang, Yunhui
    [J]. ADVANCED MATERIALS, 2018, 30 (17)
  • [9] Photo-enhanced lithium oxygen batteries with defective titanium oxide as both photo-anode and air electrode
    Gong, Hao
    Wang, Tao
    Xue, Hairong
    Fan, Xiaoli
    Gao, Bin
    Zhang, Huabin
    Shi, Li
    He, Jianping
    Ye, Jinhua
    [J]. ENERGY STORAGE MATERIALS, 2018, 13 : 49 - 56
  • [10] High-Loading Nickel Cobaltate Nanoparticles Anchored on Three-Dimensional N-Doped Graphene as an Efficient Bifunctional Catalyst for Lithium-Oxygen Batteries
    Gong, Hao
    Xue, Hairong
    Wang, Tao
    Guo, Hu
    Fan, Xiaoli
    Song, Li
    Xia, Wei
    He, Jianping
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (28) : 18060 - 18068
1234