Mesoporous Silica/Polymer Composites Utilizing Intelligent Caps onto Mesopore Walls toward Practical Low-Dielectric Materials

被引：23

作者：

Kiba, Shosuke ^{[1
,2
,3
]}

Okawauchi, Yoshinori ^{[3
]}

Yanagihara, Takeshi ^{[3
]}

Murakami, Miwa ^{[4
]}

Shimizu, Tadashi ^{[4
]}

Yamauchi, Yusuke ^{[1
,5
]}

机构：

[1] Natl Inst Mat Sci, World Premier Int WPI Res Ctr Mat, Nanoarchitechton MANA, Tsukuba, Ibaraki 3050044, Japan

[2] Toyota Tsusho Corp, Chiyoda Ku, Tokyo 1008320, Japan

[3] Adamatechs Co Ltd, Aichi 4700201, Japan

[4] Natl Inst Mat Sci, Adv Nano Characterizat Ctr, Tsukuba, Ibaraki 3050003, Japan

[5] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Wako, Saitama 3510198, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2009年 / 4卷 / 12期

关键词：

low-dielectric materials; mesoporous materials; mesoporous silica; polymers; LAYERED POLYSILICATE; CONTROLLED-RELEASE; THIN-FILMS; SILICA; MOLECULES; CONSTANT; KANEMITE;

D O I：

10.1002/asia.200900267

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To put a cap on it: Intelligent caps have been added onto mesoporous walls toward innovative low-dielectric materials. Appropriately sized caps at the mesopore entrance is quite effective, which can prevent the penetration of the polymer during the mechanical composite processing and can also provide enough space for smaller-size molecules with lower polarity to access the inner mesopore surface.

引用

页码：1798 / 1801

页数：4

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