Cyclooligophosphanes and their coordination chemistry

被引：18
作者：
Eilrich, Volker Jens [1 ]
Hey-Hawkins, Evamarie [1 ]
机构：
[1] Univ Leipzig, Inst Anorgan Chem, Fak Chem & Mineral, Johannisallee 29, D-04103 Leipzig, Germany
来源：
COORDINATION CHEMISTRY REVIEWS | 2021年 / 437卷
关键词：
Phosphanes; Cyclooligophosphanes; Polyphosphorus compounds; P ligands; Transition metal complexes; NUCLEAR-MAGNETIC-RESONANCE; CARBONYL CLUSTER DERIVATIVES; TRANSITION-METAL PHOSPHIDES; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; P-4; ACTIVATION; RING SIZE; PHOSPHORUS; REACTIVITY; COMPLEXES;
D O I：
10.1016/j.ccr.2020.213749
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this review, the scientific progress of the last 30 years on the chemistry, synthetic procedures and the reactivity of cyclooligophosphanes is presented. Cyclooligophosphanes display a rich coordination chemistry which is still only barely explored. P-31 NMR spectroscopy is a powerful tool for the characterisation of phosphorus-rich compounds. Furthermore, the potential application of phosphorus-rich metal complexes as precursors for metal phosphides is discussed. (C) 2020 Elsevier B.V. All rights reserved.
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页数：19
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